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Journal articlePerry RS, Lynne BY, Sephton MA, et al., 2006,
Baking black opal in the desert sun: the importance of silica in desert varnish, 2006, Geology, 34, 537-540
, Geology, Vol: 34, Pages: 537-540, ISSN: 0091-7613 -
Journal articleSephton MA, 2005, , PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, Vol: 363, Pages: 2729-2742, ISSN: 1364-503X
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- Citations: 43
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Journal articleBada JL, Sephton MA, Ehrenfreund P, et al., 2005, , ASTRONOMY & GEOPHYSICS, Vol: 46, Pages: 26-27, ISSN: 1366-8781
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- Citations: 25
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Journal articleSephton MA, Looy CV, Brinkhuis H, et al., 2005, , GEOLOGY, Vol: 33, Pages: 941-944, ISSN: 0091-7613
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- Citations: 237
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Journal articleSephton MA, Love GD, Meredith W, et al., 2005, , PLANETARY AND SPACE SCIENCE, Vol: 53, Pages: 1280-1286, ISSN: 0032-0633
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- Citations: 27
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Journal articleVerchovsky AB, Sephton MA, 2005, , ASTRONOMY & GEOPHYSICS, Vol: 46, Pages: 12-14, ISSN: 1366-8781
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- Citations: 1
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Conference paperPerry RS, Kolb VM, Philip A I, et al., 2005, , Conference on Astrobiology and Planetary Missions, Publisher: The International Society for Optical Engineering, Pages: 1-11
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Journal articleSephton MA, Botta O, 2005,
Recognizing life in the solar system: guidance from meteoritic organic matter
, INT J ASTROBIOL, Vol: 4, Pages: 269-276, ISSN: 1473-5504 -
Journal articleSephton MA, Meredith W, Sun CG, et al., 2005, , RAPID COMMUNICATIONS IN MASS SPECTROMETRY, Vol: 19, Pages: 323-325, ISSN: 0951-4198
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- Citations: 17
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Conference paperPerry RS, Kolb VM, Lynne BY, et al., 2005, , Conference on Astrobiology and Planetary Missions, Publisher: The International Society for Optical Engineering, Pages: 1-12
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Journal articleSephton MA, Meredith W, Sun CG, et al., 2005, , RAPID COMMUNICATIONS IN MASS SPECTROMETRY, Vol: 19, Pages: 3339-3342, ISSN: 0951-4198
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- Citations: 9
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Conference paperSephton MA, Looy CV, Visscher H, et al., 2005,
The combined petrographic and chemical analysis of end-Permian kerogens
, 8th International Meeting on Response of the Earth System to Impact Processes (IMPACT), Pages: 467-478The end of the Permian was marked by one of the greatest mass extinctions of all time. A valuable record of life and death during this event is contained within sedimentary organic matter. The stable isotopic, molecular and morphological information contained within remains of end-Permian organisms represent an important resource for scientists attempting to produce paleoenvironment reconstructions. Most meaningful data derive from multidisciplinary analyses of the same samples. In these circumstances it is desirable that sample preparation for one approach does not hinder subsequent analysis by another. To ensure compatibility of sample processing procedures the petrographic and chemical consequences of two common kerogen preparation steps, demineralization and screening (sieving), were simultaneously monitored using transmitted light microscopy and flash pyrolysis. Two end-Permian sediments, whose organic content was predominated by land-plant debris, were chosen for this purpose. A limestone was used to assess the problem of fluoride production when dematerializing carbonates and a marl was used to investigate the possibility of introducing a sampling bias following kerogen screening. Flash pyrolysis results of demineralization residues indicate that neoformed fluorides can be effectively removed by repeated treatments with excess concentrated HCl. Flash pyrolysis of screened size fractions (< 10 mu m, 10-18 mu m, 18-30 mu m, 30-125 mu m, 125-250 mu m, > 250 mu m) suggest that, for the end-Permian kerogen used, the various fractions are qualitatively representative of the unscreened kerogen. In a paleoenvironmental context, the homogeneity of the land plant derived kerogen reflects a period of organic accumulation on land followed by rapid deposition and burial in a marine setting. These findings constitute a step forward in the quest for parity between petrographic and chemical analyses of the same kerogen samples.
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Journal articleWatson JS, Sephton MA, Looy CV, et al., 2005, , ORGANIC GEOCHEMISTRY, Vol: 36, Pages: 371-384, ISSN: 0146-6380
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- Citations: 27
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Journal articleKoeberl C, Farley KA, Peucker-Ehrenbrink B, et al., 2004, , GEOLOGY, Vol: 32, Pages: 1053-1056, ISSN: 0091-7613
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- Citations: 70
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Journal articleSephton MA, James RH, Bland PA, 2004, , ASTROPHYSICAL JOURNAL, Vol: 612, Pages: 588-591, ISSN: 0004-637X
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- Citations: 15
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Journal articleVisscher H, Looy CV, Collinson ME, et al., 2004, , PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, Vol: 101, Pages: 12952-12956, ISSN: 0027-8424
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- Citations: 212
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Journal articleSephton MA, Bland PA, Pillinger CT, et al., 2004, , METEORITICS & PLANETARY SCIENCE, Vol: 39, Pages: 747-754, ISSN: 1086-9379
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- Citations: 30
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Journal articleSephton MA, 2004, , ASTRONOMY & GEOPHYSICS, Vol: 45, Pages: 8-14, ISSN: 1366-8781
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- Citations: 24
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Journal articleSephton MA, Love GD, Watson JS, et al., 2004, , GEOCHIMICA ET COSMOCHIMICA ACTA, Vol: 68, Pages: 1385-1393, ISSN: 0016-7037
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- Citations: 108
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Journal articleButterworth AL, Aballain O, Chappellaz J, et al., 2004,
Combined element (H and C) stable isotope ratios of methane in carbonaceous chondrites
, MON NOT R ASTRON SOC, Vol: 347, Pages: 807-812, ISSN: 0035-8711We have performed the first ever combined-element stable isotopic measurements of extraterrestrial molecules. Methane from two carbonaceous chondrites, Murchison and Cold Bokkeveld, was measured for its hydrogen and carbon isotopic compositions. The combined isotopic composition of meteoritic methane reveals information about the indigenous nature of volatile aliphatic organic matter in meteorites and its probable extraterrestrial source environment. Deuterium enrichments relative to the solar nebula 4.6 Gyr ago reflect a contribution from low-temperature chemical reactions in interstellar space. Similar carbon but different hydrogen isotopic compositions for methane in the two meteorite samples probably represent comparable primary origins but varying levels of secondary processing and exchange with isotopically light hydrogen. Our high precision laboratory-obtained measurements provide valuable reference points for observational spectroscopists undertaking astronomical investigations of the stable isotopic composition of extraterrestrial methane.
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